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SL Paper 1

What is the value of x when 32.2 g of Na2SO4xH2O are heated leaving 14.2 g of anhydrous Na2SO4? Mr(H2O) = 18; Mr(Na2SO4) = 142.

Na2SO4•xH2O (s) → Na2SO4 (s) + xH2O (g)

A. 0.1

B. 1

C. 5

D. 10




What is the molecular formula of a hydrocarbon containing 84.6% carbon by mass with a molar mass of 142.3 g mol−1?

A.     C20H44

B.     C11H10

C.     C10H22

D.     C5H11




What is the sum of the integer coefficients when propene undergoes complete combustion?

__C3H6 (g) + __O2 (g) → __CO2 (g) + __H2O (l)

A. 11

B. 17

C. 21

D. 23




Which is correct?


A. Mixtures are either homogeneous or heterogeneous and their chemical properties are an average of the individual component properties.

B. Mixtures are never heterogeneous and their chemical properties are an average of the individual component properties.

C. Mixtures are either homogeneous or heterogeneous and the components retain their individual chemical properties.

D. Mixtures are never homogeneous and the components retain their individual chemical properties.




How many moles of oxygen atoms are there in 0.500 mol of hydrated iron(II) ammonium sulfate, (NH4)2Fe(SO4)2•6H2O(s)?

A.     4.00

B.     7.00

C.     8.00

D.     14.00




What is the molar mass, in gmol-1, of a compound if 0.200mol of the compound has a mass of 13.2g?

A.  66.0

B.  66

C.  26.4

D.  26




What is the sum of the coefficients when the following equation is balanced using the smallest whole numbers?

__C6H12O6 (aq) → __C2H5OH (aq) + __CO2 (g)

A. 4

B. 5

C. 9

D. 10




Which contains the greatest number of moles of oxygen atoms?

A.  0.05 mol Mg(NO3)2

B.  0.05 mol C6H4(NO2)2

C.  0.1 mol H2O

D.  0.1 mol NO2




0.20 mol of magnesium is mixed with 0.10 mol of hydrochloric acid.

Mg (s)+2HCl(aq)MgCl2(aq)+H2(g)

Which is correct?




What is the sum of the coefficients when the equation is balanced with the smallest whole numbers?

__BaCl2 (aq) + __Fe2(SO4)3 (aq) → __FeCl3 (aq) + __BaSO4 (s)

A. 4

B. 6

C. 8

D. 9




Which statements about mixtures are correct?

I. The components may be elements or compounds. II. All components must be in the same phase. III. The components retain their individual properties.

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III




What is the sum of the coefficients when the equation is balanced with whole numbers?

__MnO2 (s) + __HCl (aq) → __MnCl2 (aq) + __H2O (l) + __Cl2 (g)

A.  6

B.  7

C.  8

D.  9




Which statement describes all homogeneous mixtures?


A.  Any sample has the same ratio of the components.

B.  The components are covalently bonded together.

C.  The components cannot be easily separated.

D.  The mixture needs a specific ratio of components to form.




What is the number of hydrogen atoms in 2.00 moles of Ca(HCO3)2?

Avogadro’s constant, L or NA: 6.02 × 1023 mol−1

A.  2.00

B.  4.00

C.  1.20 × 1024

D.  2.41 × 1024




8.8 g of an oxide of nitrogen contains 3.2 g of oxygen. What is the empirical formula of the compound?

A.  N2O5

B.  N2O

C.  NO2

D.  NO




Which is a homogeneous mixture?

A.     Oil and water

B.     Sand and water

C.     Ethanol and water

D.     Chalk and sand




What is the maximum volume, in dm3, of CO2(g) produced when 1.00 g of CaCO3(s) reacts with 20.0 cm3 of 2.00 mol dm–3 HCl(aq)?

CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g)

Molar volume of gas = 22.7 dm3 mol–1; Mr(CaCO3) = 100.00

A.     1 2 × 20.0 × 2.0 1000 × 22.7

B.     20.0 × 2.0 1000 × 22.7

C.     1.0 100.00 × 22.7

D.     1.0 100.00 × 2 × 22.7




0.2 mol of sodium hydrogencarbonate is decomposed by heating until constant mass.

2 NaHCO3 (s) → Na2CO3 (s) + H2O (g) + CO2 (g)

How many moles of gas are produced?

A.  0.1

B.  0.2

C.  0.3

D.  0.4




What is the percentage yield when 7 g of ethene produces 6 g of ethanol?

Mr(ethene) = 28 and Mr(ethanol) = 46

C2H4(g) + H2O(g) → C2H5OH(g)

A.      6 × 7 × 100 28 × 46

B.      6 × 46 × 100 7 × 28

C.      6 × 28 7 × 46 × 100

D.      6 × 28 × 100 7 × 46




Which factors affect the molar volume of an ideal gas?

I. Pressure II. Temperature III. Empirical formula

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III




Which volume of ethane gas, in cm3, will produce 40cm3 of carbon dioxide gas when mixed with 140cm3 of oxygen gas, assuming the reaction goes to completion?

2C2H6g+7O2g4CO2g+6H2Og

A.  10

B.  20

C.  40

D.  80




Which contains the most atoms of oxygen?

A.  64 g of O2

B.  1.2 × 1024 molecules of O2

C.  64 g of C3H5O3

D.  1.2 × 1024 molecules of C3H5O3




Which molecule has the same empirical formula as molecular formula?

A.  CH3COOH

B.  C2H5OH

C.  C2H4

D.  C4H10




Which sample contains the fewest moles of HCl?

NA = 6.02 × 1023 mol–1.

Molar volume of an ideal gas at STP = 22.7 dm3 mol–1.


A.  10.0 cm3 of 0.1 mol dm–3 HCl (aq)

B.  6.02 × 1024 molecules of HCl (g)

C.  0.365 g of HCl (g)

D.  2.27 dm3 of HCl (g) at STP




Which equation represents the deposition of iodine?

A.  I2 (g) → I2 (l)

B.  I2 (g) → I2 (s)

C.  I2 (l) → I2 (g)

D.  I2 (s) → I2 (g)




What is the volume, in cm3, of the final solution if 100 cm3 of a solution containing 1.42 g of sodium sulfate, Na2SO4, is diluted to the concentration of 0.020 mol dm–3?

Mr(Na2SO4) = 142

A.     50

B.     400

C.     500

D.     600




What is the sum of the coefficients when the equation is balanced with whole numbers?

__Sn(OH)4 (aq) + __NaOH (aq) → __Na2SnO3 (aq) + __H2O (l)

A.  4

B.  5

C.  6

D.  7




5.0 cm3 of 2.00 mol dm–3 sodium carbonate solution, Na2CO3(aq), was added to a volumetric flask and the volume was made up to 500 cm3 with water. What is the concentration, in mol dm–3, of the solution?

A.     0.0050

B.     0.0040

C.     0.020

D.     0.010




Which amount, in mol, of sodium chloride is needed to make 250 cm3 of 0.10 mol dm−3 solution?

A.  4.0 × 10−4

B.  0.025

C.  0.40

D.  25




Which diagram represents a heterogeneous mixture?




16 g of bromine react with 5.2 g of metal, M, to form MBr2. What is the relative atomic mass of the metal M? (A: Br = 80)

 

A.   13

B.   26

C.   52

D.   104




What is the number of atoms of oxygen in 2.0 mol of hydrated sodium carbonate, Na2CO3•10H2O? Avogadro’s constant, L or NA: 6.02 × 1023 mol–1

A.     6

B.     26

C.     3.6 × 1024

D.     1.6 × 1025




Which of these molecular formulae are also empirical formulae?

  1.  C2H6O
  2.  C2H4O2
  3.  C5H12

A.  I and II only

B.  I and III only

C.  II and III only

D.  I, II and III




How many grams of sodium azide, NaN3, are needed to produce 68.1 dm3 of N2 (g) at STP?

Molar volume at STP = 22.7 dm3 mol–1; Mr(NaN3) = 65.0

2NaN3 (s) → 3N2 (g) + 2Na (s)

A. 32.5

B. 65.0

C. 130.0

D. 195.0




Which graph would not show a linear relationship for a fixed mass of an ideal gas with all other variables constant?

A. P against V

B. P against  1 V

C. P against T

D. V against T




30 g of an organic compound produces 44 g CO2 and 18 g H2O as the only combustion products. Which of the following is the empirical formula for this compound?

Mr CO2 = 44 Mr H2O = 18

A.  CH2

B.  CH3

C.  CHO

D.  CH2O




What is the sum of the coefficients when the equation is balanced with the lowest whole number ratio?

__Na2S2O3(aq) + __HCl(aq) → __S(s) + __SO2(g) + __NaCl(aq) + __H2O(l)

A.     6

B.     7

C.     8

D.     9




What is the concentration, in mol dm−3, of 20.0 g of NaOH (Mr = 40.0) in 500.0 cm3?

A. 0.250

B. 0.500

C. 1.00

D. 4.00




What is the volume of gas when the pressure on 100 cm3 of gas is changed from 400 kPa to 200 kPa at constant temperature?

A. 50.0 cm3

B. 100 cm3

C. 200 cm3

D. 800 cm3




Which compound has the greatest percentage by mass of nitrogen atoms?

A.     N2H4

B.     NH3

C.     N2O4

D.     NaNO3




The two containers shown are connected by a valve. What is the total pressure after the valve is opened and the two gas samples are allowed to mix at constant temperature?


A.  1.5 × 105 Pa

B.  2.3 × 105 Pa

C.  2.5 × 105 Pa

D.  5.0 × 105 Pa




What is the empirical formula of a hydrocarbon with 75 % carbon and 25 % hydrogen by mass?

A. C3H

B. CH2

C. C2H6

D. CH4




What is the sum of the coefficients when the equation is balanced with whole numbers?

C8H18(g) + O2(g) → CO(g) + H2O(l)

A.     26.5

B.     30

C.     53

D.     61




What is the molecular formula of a compound with an empirical formula of CHO2 and a relative molecular mass of 90?

A.  CHO2

B.  C2H2O4

C.  C3H6O3

D.  C4H10O2




Which volume, in cm3, of 0.20 mol dm-3 NaOH (aq) is needed to neutralize 0.050 mol of H2S(g)? 

H2S(g) + 2NaOH(aq) → Na2S(aq) + 2H2O(l) 

A. 0.25 
B. 0.50 
C. 250 
D. 500




How many moles of magnesium hydroxide are produced with 0.50 mol of ammonia?

Mg3N2 (s) + 6H2O (l) → 3Mg(OH)2 (aq) + 2NH3 (aq)

A. 0.25

B. 0.33

C. 0.75

D. 1.5




What is the expression for the volume of hydrogen gas, in dm3, produced at STP when 0.30 g of magnesium reacts with excess hydrochloric acid solution?

Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

Molar volume of an ideal gas at STP = 22.7 dm3 mol−1

A.     0.30 × 2 × 22.7 24.31

B.     0.30 × 22.7 24.31

C.     0.30 × 24.31 22.7

D.     0.30 × 22.7 24.31 × 2




What volume of oxygen, in dm3 at STP, is needed when 5.8 g of butane undergoes complete combustion?

2C4H10(g)+13O2(g)8CO2(g)+10H2O(l)

A.  2×5.812.01×4+1.01×10×13×22.7

B.  5.812.01×4+1.01×10×132×22.7

C.  5.812.01×4+1.01×10×213×22.7

D.  5.812.01×4+1.01×10×132×22.71000




What is the concentration of chloride ions, in mol dm−3, in a solution formed by mixing 200 cm3 of 1 mol dm−3 HCl with 200 cm3 of 5 mol dm−3 NaCl?

A.  1

B.  2

C.  3

D.  6




What is the resulting concentration, in mol dm−3, when 1.0 cm3 of 0.500 mol dm−3 nitric acid solution is diluted to 50.0 cm3 with water?

A.  0.002

B.  0.01

C.  0.04

D.  0.1




The volume of a sample of gas measured at 27 °C is 10.0 dm3. What is the temperature when the volume is reduced to 9.0 dm3 at the same pressure?

 

A.   −3.0 °C

B.   24.3 °C

C.   29.7 °C

D.   57.0 °C




What is the coefficient of HCl (aq) when the equation is balanced using the smallest possible whole numbers?

__CuO (s)+ __HCl(aq) → __CuCl2(aq) + __H2O(l)

A.  1

B.  2

C.  3

D.  4

 




How many moles of FeS2 are required to produce 32 g of SO2? (Ar: S = 32, O = 16)

4FeS2 (s) + 11O2 (g) → 2Fe2O3 (s) + 8SO2 (g)

 

A.   0.25

B.   0.50

C.   1.0

D.   2.0




An antacid tablet containing 0.50 g of NaHCO3 (Mr = 84) is dissolved in water to give a volume of 250 cm3. What is the concentration, in mol dm−3, of HCO3 in this solution?

 

A.    0.250 × 84 0.50

B.    0.50 84 × 0.250

C.    250 × 84 0.50

D.    0.50 84 × 250




Which combination is correct?





Which electron transition emits energy of the longest wavelength?

M18/4/CHEMI/SPM/ENG/TZ2/06




What is the number of carbon atoms in 12g of ethanoic acid CH3COOH, Mr=60?

A.  0.20

B.  2.0

C.  1.2×1023

D.  2.4×1023




How many atoms of nitrogen are there in 0.50 mol of (NH4)2CO3?

A. 1

B. 2

C. 3.01 × 1023

D. 6.02 × 1023




What is the percentage yield when 2.0 g of ethene, C2H4, is formed from 5.0 g of ethanol, C2H5OH?
Mr(ethene) = 28; Mr(ethanol) = 46

A.     2.0 28 × 5.0 46 × 100

B.     2.0 28 5.0 46 × 100

C.     28 2.0 × 5.0 46 × 100

D.     28 2.0 5.0 46 × 100




The complete combustion of 15.0cm3 of a gaseous hydrocarbon X produces 60.0 cm3 of carbon dioxide gas and 75.0 cm3 of water vapour. What is the molecular formula of X? (All volumes are measured at the same temperature and pressure.) 

A. C4H
B. C4H
C. C4H10 
D. C6H10 




5.0mol of Fe2O3(s) and 6.0mol of CO(g) react according to the equation below. What is the limiting reactant and how many moles of the excess reactant remain unreacted?

Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)




0.10 mol of hydrochloric acid is mixed with 0.10 mol of calcium carbonate.

2HCl (aq) + CaCO3 (s) → CaCl2 (aq) + H2O (l) + CO2 (g)

Which is correct?




Which graph shows the relationship between the volume and pressure of a fixed mass of an ideal gas?

M18/4/CHEMI/SPM/ENG/TZ1/03




Which graph represents the relationship between the amount of gas, n, and the absolute temperature, T, with all other variables in the ideal gas equation, PV = nRT, held constant?